By Jeffrey M. Lemm

The examine of the constitution of molecular platforms is an everlasting quarter of study. This sequence is dedicated to bringing jointly articles from best staff within the box that draw jointly fresh theoretical and experimental effects and advances in knowing.

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Chem. 1982, 47, 4829. 35. 91 ,~ along the radial direction to the outside. ; Emrich, R. Angew. Chem. Int. Ed. Engl. 1984, 23, 993]. There are a number of interesting problems behind this discrepancy (crystal packing effect, disorder, reliability of computations etc). 36. de Aquino Neto, F. ; Sanders, J. K. M. J. Chem. , Perkin Trans. 11983, 181. 37. Unpublished results. 38. - Riichardt, C. Chem. Ber. 1980, 113, 3456. 39. Angew. Chem. Int. Ed. Engl. 1979, 18, 406. 40. Nitrogen inversion is suppressed by introducing cis-2,4-&methyl substituents.

Commun. 1983, 708. 43. ; Osawa, E. J. Chem. , Perkin Trans. H 1984, 995. ; Osawa, E. J. Mol. Struct. 1985, 126, 363. 44. ; Martin, A. ; Osawa, E. Tetrahedron, 1984, 40, 2919. 45. Sammes, M. ; Harlow, R. " Simonsen, S. H. J. Chem. , Perkin Trans. H 1976, 1126. 46. Vishwanadhan, V. ; Mattice, W. L. J. Chem. , Perkin Trans. H 1987, 739. 47. ; Zoltewicz, J. ; Kem, W. R. Tetrahedron 1994, 50, 9909. 48. Further examples of reinforced stabilization of e-par conformation of arylcycloalkanes: (a) Earley, J.

1993, B49, 116. ; Huang, H. H. J. Chem. , Perkin Trans. 2 1993, 175. The "gauche effect" is caused by intramolecular charge interactions, but we do not discuss these complications. We concentrate on hydrocarbons. 9. ; Varnali, T. ; VCH Publishers: New York, Chapter 4. (b) Anderson, J. ; Ijeh, A. I. J. Chem. , Perkin Trans. 2 1994, 1965. 10. Angew. Chem. Int. Ed. Engl. 1983, 22, 1. (b) Molecular Mechanics and Modeling; Davidson, E. " a special issue in Chem. Revs. 1993, 93, 2337-2582. 11. Rithner, C.

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