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154 TERS combines the advantages of SERS with those offered by SNOM: the single nanoscopic tip provides the local field enhancement without requiring any special sample preparation;154 this is critical to characterize the genuine surface of catalytic materials. Beyond SERS, TERS offers high spatial resolution with enhancement provided by the proximity of the tip. 157,158 Such an arrangement affords stronger surface plasmon resonance than solid metal tips. The great potential of nano-optical effects has been demonstrated, opening opportunities for highresolution insight into processes down to the molecular level.

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M. A. Ban˜ares and G. Mestl, Adv. , 2009, 52, 43. M. A. Ban˜ares in ‘‘In situ Characterization of Catalytic Materials’’ (B. M. ), American Scientific Publishers, 2004. M. A. Chesters and N. Sheppard, Chem. , 1981, 17, 521. B. A. Morrow in ‘‘Vibrational Spectroscopy of Adsorbed Species’’ (A. T. Bell and M. L. ), ACS. Symp. Series Vol. , 1981, p. 119. W. H. Weber, Mater. , 2000, 42, 233. I. E. Wachs and F. D. Hardcastle, Catalysis Vol. 10, The Royal Society of Chemistry, Cambridge, 1993, p. 102. I.

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