By Elena Burlakova, Sergey Dmitrievich Varfolomeev
The 1st quantity of this set is dedicated to the matter of chemical physics and actual chemistry of polymers and coffee molecular compounds. issues contain radical, ion and molecular reactions. Kinetics and mechanism of those reactions indicated a potential legislation of expense and the path of reactions.This quantity discusses questions of free-radical biology and new, glossy instructions in molecular cytobiology; proteomics and genomics. the second one quantity provides articles and reports on bioantioxidants, synthesis of latest compounds, mechanisms in their motion and components of program. reports on unfastened radical states utilizing ESR approach, biochemistry of regulatory structures and the position of loose radicals in radiation sickness and melanoma improvement are given certain consciousness. attempt result of new medications for curing malignant tumors and kinetic methods to the outline of disorder improvement and estimation of healing motion of medicinal arrangements are proven. The publication additionally offers reviews within the department of enzymology, receptor structures, photoreception, specifically. the amount uniquely offers common developments in chemistry, biology and drugs kinetically united and connected to unfastened radical mechanisms and different questions into consideration
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15. The dependence of main parameters of combustibility of polyethylene compositions on time of burning of samples (com-calorimeter, 35 kWt/m2): a- rate of heat generation; b- mass loss rate, c- spesific heat of burning. Analysis of received results allows noticing the general tendency in twofold reduction of heat generation rate and also in constancy of values of sum heat generation and average heat of combustion. 15 are the decrease of induction period of inflammation for all nano-composite samples in comparison with initial polymers.
31. P. P. , 77, 155 (1991). 32. T. Kurauchi, A. Okada, T. Nomura, T. Nishio, S. Saegua, R. , 910584 (1991). 33. P. Giannelis, V. Mehrotra, 0. A. Vaia, Sung Synthesis and Processing of Ceramics: Scientific Issues, Pittsburgh, PA: MRS Proc. (1992). 34. P. Giannelis, J. , 44,28 (1992). 35. V. P. Giannelis, Solid Sate Ionics, 51, 115 (1992). 36. B. P. Giannelis, Chern. , 5, 1064 (1993). 37. K. Yano, A. Usuki, A. Okada, T. Kurauchi, 0. Kamigaito, J. Polym. Sci. Part A: Polym. , 31, 2493 (1993). 38. Y.
SA. 43 The majority of received data testifies to general character of combustion decrease for all polymer nano-composites. 2) . It is obvious that combustion decrease is not a result of immobilization of organic fragments in the form of condensed aromatics on the surface of nano-layers. This fact conflicts with early investigations of cross-linking catalytic, aromatization and condensation processes on silicates surface . 2. Comparative data of the main parameters of combustion of some polymers and compositions on their base received on con-calorimeter at external heat flow 35 kWt/m2 .