By Prof. Dr. D. Klemm, Prof. Dr. B. Philipp, Dr. T. Heinze, Dr. U. Heinze, Dr. W. Wagenknecht(auth.)
Cellulose is not just a big constituent of wooden and average fabric fibers. It additionally serves as a polymeric beginning fabric for items utilized in many parts of and every-day-life.
The booklet, written via major specialists within the box, is split in to volumes:
within the first quantity basic info on cellulose constitution and houses is given in addition to the rules of homogeneous and heterogenous cellulose reactions and degradation pathways. Analytical tools for the characterization of cellulose also are described.
the second one quantity covers artificial routes to many of the sessions of cellulose derivatives. dependent in accordance with the foundations of natural chemistry the achievements of modern-day response thought are thought of and supplemented via an intensive selection of operating tactics. It additionally bargains with the most recent advancements and destiny traits in cellulose chemistry - from development in cellulose processing to the supramolecular chemistry of recent derivatives of cellulose.
This wide insurance makes the ebook a typical paintings for graduate scholars getting into this interesting box of study, but in addition chemists, biologists and engineers who're lively in chemical processing of cellulose will discover a wealth of knowledge.
Chapter 4.1–4.1.4 Systematics of Cellulose Functionalization: part 4.1–4.1.4 (pages 1–31):
Chapter 4.2–220.127.116.11 Systematics of Cellulose Functionalization: part 4.2–18.104.22.168 (pages 31–51):
Chapter 4.2.3–4.2.7 Systematics of Cellulose Functionalization: part 4.2.3–4.2.7 (pages 51–71):
Chapter 4.3–4.3.6 Systematics of Cellulose Functionalization: part 4.3–4.3.6 (pages 71–99):
Chapter 4.4–22.214.171.124 Systematics of Cellulose Functionalization: part 4.4–126.96.36.199 (pages 99–145):
Chapter 4.4.2–188.8.131.52 Systematics of Cellulose Functionalization: part 4.4.2–184.108.40.206 (pages 145–164):
Chapter 4.4.3–220.127.116.11 Systematics of Cellulose Functionalization: part 4.4.3–18.104.22.168 (pages 164–197):
Chapter 4.4.4 Systematics of Cellulose Functionalization: part 4.4.4 (pages 197–207):
Chapter 4.5–4.5.1 Systematics of Cellulose Functionalization: part 4.5–4.5.1 (pages 207–210):
Chapter 4.5.2–22.214.171.124 Systematics of Cellulose Functionalization: part 4.5.2–126.96.36.199 (pages 210–249):
Chapter 4.5.3–188.8.131.52 Systematics of Cellulose Functionalization: part 4.5.3–184.108.40.206 (pages 249–262):
Chapter 4.5.4–220.127.116.11 Systematics of Cellulose Functionalization: part 4.5.4–18.104.22.168 (pages 262–273):
Chapter 4.5.5–22.214.171.124 Systematics of Cellulose Functionalization: part 4.5.5–126.96.36.199 (pages 274–294):
Chapter 4.5.6 Systematics of Cellulose Functionalization: part 4.5.6 (pages 294–302):
Chapter 4.6–4.6.2 Systematics of Cellulose Functionalization: part 4.6–4.6.2 (pages 302–314):
Chapter 5.1–5.5 destiny advancements in Cellulose Chemistry – An Outlook: part 5.1–5.5 (pages 315–325):
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Additional info for Comprehensive Cellulose Chemistry: Functionalization of Cellulose, Volume 2
In radiation grafting the course of reaction significantly depends on the moisture content of the substrate. Radiation grafting of a completely dry preirradiated cellulose did not start until the temperature of thermal polymerization of the monomer was reached, while the starting temperature was significantly decreased by stepwise enhancement of the water content up to a level between 5 and 20 % (Plotnikov and Lesins, 1981). The mobility of the radicals formed increases with the moisture content in the less well ordered regions of a pulp or cotton fiber, resulting in an increase in polymer add-on with the moisture content in a grafting experiment employing the 'simultaneous method', and the decay rate of the radicals also increases with the content of H2O.
J. Appl. Polym. ScL 1997, 66, 307-317. e. compounds formed without covalent derivatization of the macromolecule but nevertheless representing chemical entities by themselves, with chemical and physical properties differing often decisively from that of unmodified cellulose. Quite predominantly, processes of interaction of solid cellulose are the topic of this text. Thus the interdependency between the chemical interaction and the supramolecular and morphological structure of the cellulose sample plays a decisive role.
Kroschwitz, JJ. ), New York: John Wiley & Sons, 1985, pp. 60-68. , Ind. Eng. Chem. Prod. Res. Dev. 1982, 27, 629632. , Cellul Chem. Technol. 1980,14, 633-653. , Polymer 1994, 35, 1977-1985. , Plant Cell 1995, 7, 987-1000. , Polymer 1989, 30, 570-575. , Patent DD 269 561, 1989; Chem. Abstr. 1990, 772, 38829. , British Patent 1906, 25, 647. , /. Soc. Chem. Ind. 1907, 26, 821. , /. Appl. Polym. Sei. 1996, 60, 2403-2407. , 7. Appl. Polym. Sei. 1987, 33, 899-906. D. Thesis, Academy of Science (GDR) 1980.