By Jie Jack Li, E. J. Corey

A worthy addition to the literature by way of any degree and absolutely will end up its benefit in years yet to come. the hot wisdom that arises with its assistance will be remarkable and of serious gain to humankind.—From the Foreword via E. J. Corey, Nobel Prize LaureateAn necessary consultant to call reactions and reagents for homologationsName Reactions for Homologations, half I of Wiley's entire identify Reactions sequence contains a finished treatise on identify reactions for homologations. With contributions from world-recognized specialists within the box, this reference bargains an up to date, concise compilation of the main usual and well known identify reactions and reagents. half I discusses Organometallics, Carbon-chain Homologation, and Radical Chemistry.Arranged alphabetically through identify reactions, the directory provides:Description of the reactionHistorical perspectiveA mechanism for the reactionVariations and enhancements at the reactionSynthetic utilities of the reactionExperimental detailsReferences to the present fundamental literatureArmed with this worthwhile source, either scholars and execs may have at their fingertips a finished consultant to special mechanisms and phenomena in homologation.

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F. In Comprehensive Organic Synthesis; Trost, B. ; Pergamon Press: Oxford, 1991; Vol. 4. [R] Heck, R. F. Org. React. (N. ) 1982, 27, 345. [R] Daves, G. ; Hallberg, A. Chem Rev. 1989, 89, 1433. ; Meyer, F. E. Angew. , Int. Ed Engl. 1994, 33, 2379. [R] de Meijere, A, Braese, S. In Transition Metal Catalyzed Reactions; Davies S. ; Blackwell Science: Oxford, 1999. ; Candiani, I. Ace. Chem. Res. 1995, 28, 2. [R] Jeffery, T. In Advances in Metal-Organic Chemistry; Liebeskind, L. ; Jai Press Inc: Greenwich, CT, 1996; Vol.

Wiley-VCH: New York, 1998. ; Boden, C. D. ; Kojima, A. Tetrahedron, 1997, 53, 7371. [R] Overman, L. E. Pure Appl. Chem. 1994, 66, 1423. [R] Link, J. ; Overman, L. E. , Stang, P. ; Wiley-VCH: New York, 1998. [R] Link, J. ; Overman, L. E. Chemtech 1998, 28, 19. [R] Gibson, S. ; Middleton, R. J. Contemp. Org. Synth. 1996, 3, 447. [R] Reetz, M. T. In Metal-Catalyzed Reactions; Davies, S. : Oxford, 1999. [R] Beletskaya, I. ; Cheprakov, A. V. Chem. Rev. 2000,100, 3009. [R] Dounay, A. ; Overman, L. E.

CISi(OEt)3 3. 2 equiv) THF, 30 °C, 48-72 h "" 66-98% Si(OEt) 3 43 Chapter 1. Organometallics Applications in Natural Products The Hiyama cross-coupling reaction has not been highly represented in the preparation of natural products compared to the Negishi, Stille, and Suzuki reactions. DeShong utilized this key step in synthetic studies towards several natural products. 40 Elaboration of 54 to phenanthrol 55 was accomplished in six steps. Finally phenanthrol ring expansion provided racemic jV-acetyl colchinol-0-methyl ether (56).

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